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2024
Cobalt/Photoredox Dual-Catalyzed Cross-Radical Coupling of Alkenes via Hydrogen Atom Transfer and Homolytic Substitution
Yamaguchi, Y.; Hirata, Y.; Higashida, K.; Yoshino, T.; Matsunaga, S.
Org. Lett. 2024, asap. DOI: 10.1021/acs.orglett.4c01370
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/06/ol2024-yamaguchi-1024x536.png)
2023
Enantioselective Synthesis of 1,2-Benzothiazine 1-Imines via RuII/Chiral Carboxylic Acid-Catalyzed C–H Alkylation/Cyclization
Huang, L.-T; Kitakawa, Y.; Yamada, K.; Kamiyama, F.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2023, 62, e202305480. DOI: 10.1002/anie.202305480
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2023-62-e202305480.png)
Synthesis of Benzo[c]azepine-1,3(2H)-diones via C–H Alkylation/Cyclization with α,β-Unsaturated Acyl Fluorides
Hosoi, S.; Hirata, Y.; Kurihara, T.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Asian J. Org. Chem. 2023, 12, e202300218. DOI: 10.1002/ajoc.202300218
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ajoc2023-12-e202300218.png)
Catalytic Enantioselective Amination of Enol Silyl Ethers Using a Chiral Paddle-Wheel Diruthenium Complex
Makino, K.; Kumagai, Y.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Org. Lett. 2023, 25, 3234-3238. DOI: 10.1021/acs.orglett.3c00940
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2023-25-3234.png)
Synthesis of Polysubstituted Enamides by Hydrogen Atom Transfer Alkene Isomerization Using Dual Cobalt/Photoredox Catalysis
Seino, Y.; Yamaguchi Y.; Suzuki, A.; Yamashita, Y.; Kamei, Y.; Kamiyama, F.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Chem. Eur. J. 2023, 29, e202300804. DOI: 10.1002/chem.202300804
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/06/cej2023-29-e202300804-1024x358.jpg)
Formation of Isolable Dearomatized [4 + 2] Cycloadducts from Benzenes, Naphthalenes, and N-Heterocycles Using 1,2-Dihydro-1,2,4,5-tetrazine-3,6-diones as Arenophiles under Visible Light Irradiation
Ikeda, K.; Kojima, R.; Kawai, K.; Murakami, T.; Kikuchi, T.; Kojima, M.; Yoshino, T.; Matsunaga, S.
J. Am. Chem. Soc. 2023, 145, 9326-9333. DOI: 10.1021/jacs.3c02556
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2023-145-9326.png)
An Electron-Deficient CpE Iridium(III) Catalyst: Synthesis, Characterization, and Application to Ether-Directed C–H Amidation
Tomita, E.; Kojima, M.; Nagashima, Y.; Tanaka, K.; Sugiyama, H.; Segawa, Y.; Furukawa, A.; Maenaka, K.; Maeda, S.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2023, 62, e202301259. DOI: 10.1002/anie.202301259
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2023-62-e202301259.png)
Iron/Photosensitizer-Catalyzed Directed C–H Activation Triggered by the Formation of an Iron Metallacycle
Kato, Y.; Yoshino, T.; Matsunaga, S.
ACS Catal. 2023, 13, 4552-4559. DOI: 10.1021/acscatal.3c00381
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acscatal2023-13-4552.png)
Noble-Metal-Free C–H Allylation of Tetrahydroisoquinolines Using a Cobalt-Organophotoredox Dual Catalyst System
Sato, S.; Sasaki, W.; Sekino, T.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Chem. Pharm. Bull. 2023, 71, 79-82. DOI: 10.1248/cpb.c22-00520
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cpb2023-71-79.png)
Photocatalytic Deuterium Atom Transfer Deuteration of Electron-Deficient Alkenes with High Functional Group Tolerance
Suzuki, A.; Kamei, Y.; Yamashita, M.; Seino, Y.; Yamaguchi, Y.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Angew. Chem., Int. Ed. 2023, 62, e202214433. DOI: 10.1002/anie.202214433
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2023-62-e202214433.png)
Photo-Induced Nickel-Catalyzed Carbon-Heteroatom Coupling
Luo, H.; Wang, G.; Feng, Y.; Zheng, W.; Kong, L.; Ma, Y.; Matsunaga, S. Lin, L.
Chem. Eur. J. 2023, 29, e202202385. DOI: 10.1002/chem.202202385
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cej2023-29-e202202385.png)
2022
Native Amide-Directed C(sp3)–H Amidation Enabled by Electron-Deficient Rh(III) Catalyst and Electron-Deficient 2-Pyridone Ligand
Wakikawa, T.; Sekine, D.; Murata, Y.; Bunno, Y.; Kojima, M.; Nagashima, Y.; Tanaka, K.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2022, 61, e202213659. DOI: 10.1002/anie.202213659
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2022-61-e202213659.png)
Iron/Photosensitizer Hybrid System Enables the Synthesis of Polyaryl-Substituted Azafluoranthenes
Kato, Y.; Yoshino, T.; Gao, M.; Hasegawa, J.; Kojima, M.; Matsunaga, S.
J. Am. Chem. Soc. 2022, 144, 18450-18458. DOI: 10.1021/jacs.2c06993
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2022-144-18450.png)
Light-Promoted Nickel-Catalyzed Aromatic Halogen Exchange
Feng, Y.; Luo, H.; Zheng, W.; Matsunaga, S. Lin, L.
ACS Catal. 2022, 12, 11089-11096. DOI: 10.1021/acscatal.2c03354
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acscatal2022-12-11089.png)
Design and Synthesis of Cyclopropane Congeners of Resolvin E3, an Endogenous Pro-Resolving Lipid Mediator, as Its Stable Equivalents
Arai, S.; Fujiwara, K.; Kojima, M.; Aoki-Saito, H.; Yatomi, M.; Saito, T.; Koga, Y.; Fukuda, H.; Watanabe, M.; Matsunaga, S.; Hisada, T.; Shuto, S.
J. Org. Chem. 2022, 87, 10501-10508. DOI: 10.1021/acs.joc.2c01110
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/joc2022-87-10501.png)
Enantioselective C–H Functionalization Using High-Valent Group 9 Metal Catalysts
Yoshino, T.
Bull. Chem. Soc. Jpn. 2022, 95, 1280-1288. DOI: 10.1246/bcsj.20220168
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/bcsj2022-95-1280.png)
Cobalt(III)/Chiral Carboxylic Acid-Catalyzed Enantioselective Synthesis of Benzothiadiazine-1-Oxides via C–H Activation
Hirata, Y.; Sekine, D.; Kato, Y.; Lin, L.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2022, 61, e202205341. DOI: 10.1002/anie.202205341
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2022-61-e202205341.png)
Achiral Cp*Rh(III)/Chiral Lewis Base Cooperative Catalysis for Enantioselective Cyclization via C–H Activation
Kurihara, T.; Kojima, M.; Yoshino, T.; Matsunaga, S.
J. Am. Chem. Soc. 2022, 144, 7058-7065. DOI: 10.1021/jacs.2c01223
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2022-144-7058.jpg)
Intramolecular Hydrogen Atom Transfer Hydroarylation of Alkenes toward δ-Lactams Using Cobalt-Photoredox Dual Catalysis
Yamaguchi, Y.; Seino, Y.; Suzuki, A.; Kamei, Y.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Org. Lett. 2022, 24, 2441-2445. DOI: 10.1021/acs.orglett.2c00700
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2022-24-2441.png)
Regioselective Deaminative Allylation of Aliphatic Amines via Dual Cobalt and Organophotoredox Catalysis
Sekino, T.; Sato, S.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Org. Lett. 2022, 24, 2120-2124. DOI: 10.1021/acs.orglett.2c00319
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2022-24-2120.jpg)
1,2-Disubstituted 1,2-Dihydro-1,2,4,5-tetrazine-3,6-dione as a Dynamic Covalent Bonding Unit at Room Temperature
Kawai, K.; Ikeda, K.; Sato, A.; Kabasawa, A.; Kojima, M.; Kokado, K.; Kakugo, A.; Sada, K.; Yoshino, T.; Matsunaga, S.
J. Am. Chem. Soc. 2022, 144, 1370-1379. DOI: 10.1021/jacs.1c11665
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2022-144-1370.gif)
Cp*Rh(III)/Boron Hybrid Catalysis for Directed C–H Addition to β-Substituted α,β-Unsaturated Carboxylic Acids
Tanaka, R.; Hirata, Y.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Chem. Commun. 2022, 58, 76-79. DOI: 10.1039/d1cc05956d
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cc2022-58-76.png)
Ru(II)/Chiral Carboxylic Acid-Catalyzed Enantioselective C–H Functionalization of Sulfoximines
Huang, L.-T.; Hirata, Y.; Kato, Y.; Lin, L.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Synthesis 2022, 54, 4703-4710. DOI: 10.1055/a-1588-0072
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/synthesis2022-54-4703.png)
2021
Cp*RhIII/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes
Hirose, J.; Wakikawa, T.; Satake, S.; Kojima, M.; Hatano, M.; Ishihara, K.; Yoshino, T.; Matsunaga, S.
ACS Catal. 2021, 11, 15187-15193. DOI: 10.1021/acscatal.1c04699
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acscatal2021-11-15187.gif)
Cp*Ir(III)/Chiral Carboxylic Acid-Catalyzed Enantioselective C–H Alkylation of Ferrocene Carboxamides with Diazomalonates
Mou, Q.; Zhao, R.; Niu, R.; Fukagawa, S.; Shigeno, T.; Yoshino, T.; Matsunaga, S.; Sun, B.
Org. Chem. Front. 2021, 8, 6923-6930. DOI: 10.1039/D1QO01344K
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ocf2021-8-6923.gif)
Transition-metal-free Nucleophilic 211At-astatination of Spirocyclic Aryliodonium Ylides
Matsuoka, K.; Obata, H.; Nagatsu, K.; Kojima, M.; Yoshino, T.; Ogawa, M.; Matsunaga, S.
Org. Biomol. Chem. 2021, 19, 5525-5528. DOI: 10.1039/D1OB00789K
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/obc2021-19-5525.png)
Chiral Carboxylic Acid Assisted Enantioselective C–H Activation with Achiral CpxMIII (M = Co, Rh, Ir) Catalysts
Yoshino, T.; Matsunaga, S.
ACS Catal. 2021, 11, 6455-6466. DOI: 10.1021/acscatal.1c01351
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acscatal2021-11-6455.gif)
Development of Pseudo-C2-symmetric Chiral Binaphthyl Monocarboxylic Acids for Enantioselective C(sp3)–H Functionalization Reactions under Rh(III) Catalysis
Kato, Y.; Lin, L.; Kojima, M.; Yoshino, T.; Matsunaga, S.
ACS Catal. 2021, 11, 4271-4277. DOI: 10.1021/acscatal.1c00765
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acscatal2021-11-4271.gif)
Silane- and Peroxide-Free Hydrogen Atom Transfer Hydrogenation Using Ascorbic Acid and Cobalt-Photoredox Dual Catalysis
Kamei, Y.; Seino, Y.; Yamaguchi, Y.; Yoshino, T.; Maeda, S.; Kojima, M.; Matsunaga, S.
Nat. Commun. 2021, 12, 966. DOI: 10.1038/s41467-020-20872-z
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/natcommun2021-12-966.png)
Metal-Containing Schiff Base/Sulfoxide Ligands for Pd(II)-Catalyzed Asymmetric Allylic C–H Aminations
Bunno, Y.; Tsukimawashi, Y.; Kojima, M.; Yoshino, T.; Matsunaga, S.
ACS Catal. 2021, 11, 2663-2668. DOI: 10.1021/acscatal.0c05261
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acscatal2021-11-2663.gif)
Chemoselective Cleavage of Si–C(sp3) Bonds in Unactivated Tetraalkylsilanes Using Iodine Tris(trifluoroacetate)
Matsuoka, K.; Komami, N.; Kojima, M.; Mita, T.; Suzuki, K.; Maeda, S.; Yoshino, T.; Matsunaga, S.
J. Am. Chem. Soc. 2021, 143, 103-108. DOI: 10.1021/jacs.0c11645
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2021-143-103.gif)
Generation of Monoaryl-λ3-iodanes from Arylboron Compounds through ipso-Substitution
Nakano, A.; Okabe, Y.; Matsuoka, K.; Komami, N.; Watanabe, K.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Heterocycles 2021, 103, 670-677. DOI: 10.3987/COM-20-S(K)45
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles2021-103-670.png)
2020
Rhodium(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C(sp3)–H Alkylation of 8-Ethylquinolines with α,β-Unsaturated Carbonyl Compounds
Huang, L.-T.; Fukagawa, S.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Org. Lett. 2020, 22, 8256-8260. DOI: 10.1021/acs.orglett.0c02872
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2020-22-8256.jpg)
Chiral Paddle-Wheel Diruthenium Complexes for Asymmetric Catalysis
Miyazawa, T.; Suzuki, T.; Kumagai, Y.; Takizawa, K.; Kikuchi, T.; Kato, S.; Onoda, A.; Hayashi, T.; Kamei, Y.; Kamiyama, F.; Anada, M.; Kojima, M.; Yoshino, T.; Matsunaga S.
Nature Catalysis 2020, 3, 851-858. DOI: 10.1038/s41929-020-00513-w
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/natcatal2020-3-851.png)
Allyl 4-Chlorophenyl Sulfone as a Versatile 1,1-Synthon for Sequential α-Alkylation/Cobalt-Catalyzed Allylic Substitution
Sekino, T.: Sato, S.; Kuwabara, K.; Takizawa, K.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Synthesis 2020, 52, 1934-1946. DOI: 10.1055/s-0040-1707524
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/synthesis2020-52-1934.gif)
Iridium(III) Catalysts with an Amide‐Pendant Cyclopentadienyl Ligand: Double Aromatic Homologation Reactions of Benzamides by Fourfold C−H Activation
Tomita, E.; Yamada, K.; Shibata Y.; Tanaka K.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2020, 59, 10474-10478. DOI: 10.1002/anie.202003009
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2020-59-10474.webp)
The Merger of Photoredox and Cobalt Catalysis
Kojima, M.; Matsunaga, S.
Trends Chem. 2020, 2, 410-426. DOI: 10.1016/j.trechm.2020.01.004
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/trendschem2020-2-410.png)
Diverse Approaches for Enantioselective C–H Functionalization Reactions Using Group 9 CpxMIII Catalysts
Yoshino, T.; Satake, S.; Matsunaga, S.
Chem. Eur. J. 2020, 26, 7346-7357. DOI: 10.1002/chem.201905417
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cej2020-26-7346.png)
Cp*CoIII/Chiral Carboxylic Acid-Catalyzed Enantioselective 1,4-Addition Reactions of Indoles to Maleimides
Kurihara, T.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Asian J. Org. Chem. 2020, 9, 368-371. DOI: 10.1002/ajoc.201900565
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ajoc2019-368-371.jpg)
2019
Catalytic Enantioselective Methylene C(sp3)–H Amidation of 8-Alkylquinolines Using Cp*RhIII/Chiral Carboxylic Acid System
Fukagawa, S.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2019, 58, 18154-18158. DOI: 10.1002/anie.201911268
Highlighted in Synfacts.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2019-58-18154.png)
Imidate as the Intact Directing Group for the Cobalt-Catalyzed C–H Allylation
Tanaka, R.; Tanimoto, I.; Kojima, M.; Yoshino, T.; Matsunaga, S.
J. Org. Chem. 2019, 84, 13203-13210. DOI: 10.1021/acs.joc.9b01972
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/joc2019-84-13203.gif)
Chiral 2-Aryl Ferrocene Carboxylic Acids for the Catalytic Asymmetric C(sp3)–H Activation of Thioamides
Sekine, D.; Ikeda, K.; Fukagawa, S.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Organometallics 2019, 38, 3921-3926. DOI: 10.1021/acs.organomet.9b00407
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/om2019-38-3921.gif)
Cobalt-catalyzed Synthesis of Homoallylic Amines from Imines and Terminal Alkenes
Tanaka, R.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Chem. Lett. 2019, 48 1046-1049. DOI: 10.1246/cl.190378
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cl2019-48-1046.gif)
Cp*CoIII-Catalyzed C–H Functionalization and Asymmetric Reactions Using External Chiral Sources
Yoshino, T.; Matsunaga, S.
Synlett 2019, 30, 1384-1400. DOI: 10.1055/s-0037-1611814
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/synlett2019-30-1384.gif)
C–H γ,γ,γ-Trifluoroalkylation of Quinolines via Visible-Light-Induced Sequential Radical Additions
Kumagai, Y.; Murakami, N.; Kamiyama, F.; Tanaka, R.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Org. Lett. 2019, 21, 3600-3605. DOI: 10.1021/acs.orglett.9b01015
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2019-21-3600.gif)
Synthesis of Heteroaryl Iodanes(III) via ipso-Substitution Reactions Using Iodine Triacetate Assisted by HFIP
Matsuoka, K.; Komami, N.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Asian J. Org. Chem. 2019, 8, 1107-1110. DOI: 10.1002/ajoc.201900200
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ajoc2019-8-1107.png)
Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis
Takizawa, K.; Sekino, T.; Sato, S.; Yoshino, T.; Kojima, M.; Matsunaga, S.
Angew. Chem., Int. Ed. 2019, 58, 9199-9203. DOI: 10.1002/anie.201902509
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2019-58-9199.png)
Synthesis of Functionalized Monoaryl-λ3-iodanes through Chemo- and Site-selective ipso-Substitution Reactions
Komami, N.; Matsuoka, K.; Nakano, A.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Chem. Eur. J. 2019, 25, 1217-1220. DOI: 10.1002/chem.201805970
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cej2019-25-1217.jpg)
Enantioselective C(sp3)–H Amidation of Thioamides Catalyzed by a CobaltIII/Chiral Carboxylic Acid Hybrid System
Fukagawa, S.; Kato, Y.; Tanaka, R.; Kojima, M.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2019, 58, 1153-1157. DOI: 10.1002/anie.201812215
Highlighted in Synfacts.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2019-58-1153.jpg)
One-Step Synthesis of 4H-3,1-Benzoxazin-4-ones from Weinreb Amides and 1,4,2-Dioxazol-5-ones via Cobalt-Catalyzed C–H Bond Activation
Tanimoto, I.; Kawai, K.; Sato, A.; Yoshino, T.; Matsunaga, S.
HeteroCycles 2019, 99, 118-125. DOI: 10.3987/COM-18-S(F)48
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles-2019-99-118.png)
2018
Chiral Carboxylic Acid-Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization
Lin, L.; Fukagawa, S.; Sekine, D.; Tomita, E.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2018, 57, 12048-12052. DOI: 10.1002/anie.201807610
Highlighted in Synfacts.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2018-57-12048.jpg)
Pentamethylcyclopentadienyl Rhodium(III)-Chiral Disulfonate Hybrid Catalysis for Enantioselective C–H Bond Functionalization
Satake, S.; Kurihara, T.; Nishikawa, K.; Mochizuki, T.; Hatano, M.; Ishihara, K.; Yoshino, T.; Matsunaga, S.
Nature Catalysis 2018, 1, 585-591. DOI: 10.1038/s41929-018-0106-5
Author Correction
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/natcatal2018-1-585.png)
5-((3-Bromoallyl)Sulfonyl)-1H-Tetrazoles for Bromodiene Synthesis
Suzuki, T.; Fukagawa, S.; Yoshino, T.; Anada, M.; Matsunaga, S.
HeteroCycles 2018, 97, 1304-1312. DOI: 10.3987/COM-18-S(T)90
Weinreb Amide Directed Versatile C–H Bond Functionalization under (η5-Pentamethylcyclopentadienyl)cobalt(III) Catalysis
Kawai, K.; Bunno, Y.; Yoshino, T.; Matsunaga, S.
Chem. Eur. J. 2018, 24, 10231-10237. DOI: 10.1002/chem.201801750
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cej2018-24-10231.jpg)
Cobalt-catalyzed C(sp3)–H Bond Functionalization Reactions
Yoshino, T.; Matsunaga, S.
Asian J. Org. Chem. 2018, 7, 1193-1205. DOI: 10.1002/ajoc.201800195
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ajoc2018-7-1193.jpg)
Synthesis of 1,1'-Spirobiindane-7,7'-Disulfonic Acid and Disulfonimide: Application for Catalytic Asymmetric Aminalization
Kurihara, T.; Satake, S.; Hatano, M.; Ishihara K.; Yoshino T.; Matsunaga, S.
Chem. Asian. J. 2018, 13, 2378-2381. DOI: 10.1002/asia.201800341
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/caj2018-13-2378.jpg)
DOCK1 inhibition suppresses cancer cell invasion and macropinocytosis induced by self-activating Rac1P29S mutation
Tomino, T.; Tajiri, H.; Tatsuguchi, T.; Shirai, T.; Oisaki, K.; Matsunaga, S.; Sanematsu, F.; Sakata, D.; Yoshizumi, T.; Maehara, Y.; Kanai, M.; Cote, J.-F.; Fukui, Y.; Uruno Y.
Biochem. Biophys. Res. Commun. 2018, 497, 298-304. DOI: 10.1016/j.bbrc.2018.02.073
Palladium-Catalyzed Germylation of Aryl Bromides and Aryl Triflates Using Hexamethyldigermane
Komami, N.; Matsuoka, K.; Yoshino, T.; Matsunaga S.
Synthesis 2018, 50, 2067-2075. DOI: 10.1055/s-0037-1609301
Highlighted in the news section on Thieme Chemistry homepage.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/synthesis2018-50-2067.gif)
Synthesis of Fluorine-Containing 6-Arylpurine Derivatives via Cp*Co(III)-Catalyzed C–H Bond Activation
Murakami, N.; Yoshida, M.; Yoshino, T.; Matsunaga S.
Chem. Pharm. Bull. 2018, 66, 51-54. DOI: 10.1248/cpb.c17-00797
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cpb2018-66-51.png)
2017
Structural and thermodynamic analyses reveal critical features of glycopeptide recognition by the human PILRα immune cell receptor
Furukawa, A.; Kakita, K.; Yamada, T.; Ishizuka, M.; Sakamoto, J.; Hatori, N.; Maeda, N.; Ohsaka, F.; Saitoh, T.; Nomura, T.; Kuroki, K.; Nambu, H.; Arase, H.; Matsunaga, S.; Anada, M.; Ose, T.; Hashimoto, S.; Maenaka, K.
J. Biol. Chem. 2017, 292, 21128-21136. DOI: 10.1074/jbc.M117.799239
Total Synthesis of Brasilicardins A and C
Anada M.; Hanari T.; Kakita K.; Kurosaki Y.; Katsuse K.; Sunadoi Y.; Jinushi Y.; Takeda K.; Matsunaga S.; Hashimoto S.
Org. Lett. 2017, 19, 5581-5584. DOI: 10.1021/acs.orglett.7b02728
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2017-19-5581.gif)
2-Hydroxyindoline-3-triethylammonium Bromide: A Reagent for Formal C3-Electrophilic Reactions of Indoles
Abe T.; Suzuki, T.; Anada M.; Matsunaga, S.; Yamada K.
Org. Lett. 2017, 19, 4275-4278. DOI: 10.1021/acs.orglett.7b01940
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2017-19-4275.gif)
High-Valent Cobalt-Catalyzed C–H Bond Functionalization
Yoshino T.; Matsunaga S.
Advances in Organometallic Chemistry 2017, 68, 197-247. DOI: 10.1016/bs.adomc.2017.07.002
Cp*CoIII-Catalyzed C–H Alkenylation/Annulation Reactions of Indoles with Alkynes: A DFT Study
Sakata, K.; Eda M.; Kitaoka Y.; Yoshino T.; Matsunaga S.
J. Org. Chem. 2017, 82, 7379-7387. DOI: 10.1021/acs.joc.7b01047
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/joc2017-82-7379.gif)
Catalytic Enantioselective Desymmetrization of meso-Aziridines with Fluoromalonates
Fukagawa, S.; Xu, Y.; Anada, M.; Yoshino, T.; Matsunaga, S.
HeteroCycles 2017, 94 1337-1350. DOI: 10.3987/COM-17-13725.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles2017-94-1337.png)
Targeting Ras-Driven Cancer Cell Survival and Invasion through Selective Inhibition of DOCK1
Tajiri, H.; Uruno, T.; Shirai, T.; Takaya, S.; Matsunaga, S.; Setoyama, D.; Watanabe, M.; Kukimoto-Niino, M.; Oisaki, K.; Ushijima, M.; Sanematsu, F.; Honma, T.; Terada,T.; Oki,E.; Shirasawa, S.; Maehara, Y.; Kang, D.; Côté, J.-F.; Yokoyama, S.; Kanai, M.; Fukui, Y.
Cell Reports 2017, 19, 969-980. DOI: 10.1016/j.celrep.2017.04.016
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cellreports2017-19-969.jpg)
Structural and thermodynamic analyses reveal critical features of glycopeptide recognition by the human PILRα immune cell receptor
Furukawa, A.; Kakita, K.; Yamada, T.; Ishizuka, M.; Sakamoto, J.; Hatori, N.; Maeda, N.; Ohsaka, F.; Saitoh, T.; Nomura, T.; Kuroki, K.; Nambu, H.; Arase, H.; Matsunaga, S.; Anada, M.; Ose, T.; Hashimoto, S.; Maenaka, K.
J. Biol. Chem. 2017, 292, 21128-21136. DOI: 10.1074/jbc.M117.799239
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2023-62-e202305480.png)
Stereoselective Synthesis of Tetrasubstituted Alkenes via a Cp*CoIII-Catalyzed C−H Alkenylation/Directing Group Migration Sequence
Ikemoto. H.; Tanaka, R.; Sakata, K.; Kanai, M.; Yoshino, T.; Matsunaga, S.
Angew. Chem., Int. Ed. 2017, 56, 7156-7160. DOI: 10.1002/anie.201703193
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2017-51-7156.png)
Cp*CoIII-catalyzed Directed C–H Trifluoromethylthiolation of 2-Phenylpyridines and 6-Arylpurines
Yoshida, M.; Kawai, K.; Tanaka, R.; Yoshino, T.; Matsunaga, S.
Chem. Commun. 2017, 53, 5974-5977. DOI: 10.1039/C7CC03072J
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cc2017-53-5974.gif)
A Novel Spiro-heterocyclic Compound Identified by the Silkworm Infection Model Inhibits Transcription in Staphylococcus aureus
Paudel, A.; Hamamoto, H.; Panthee, S.; Kaneko, K.; Matsunaga, S.; Kanai, M.; Suzuki, Y.; Sekimizu, K.
Front. Microbiol. 2017, 7, 712. DOI: 10.3389/fmicb.2017.00712
Hybrid Catalysis Enabling Room-Temperature Hydrogen Gas Release from N-Heterocycles and Tetrahydronaphthalenes
Kato, S.; Saga, Y.; Kojima, M.; Fuse,H.; Matsunaga, S.; Fukatsu, A.; Kondo, M.; Masaoka, S.; Kanai, M.
J. Am. Chem. Soc. 2017, 139, 2204-2207. DOI: 10.1021/jacs.7b00253
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2017-139-2204.gif)
(Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity
Yoshino, T.; Matsunaga, S.
Adv. Synth. Catal. 2017, 359, 1245-1262. DOI: 10.1002/adsc.201700042
Selected for a cover picture, DOI: 10.1002/adsc.201700284
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/advsynthcat2017-359-1245.png)
Diastereo- and Enantioselective Construction of 6,7-Dioxabicyclo[2.2.1]heptane Derivatives by a Dirhodium(II)-Catalyzed Intramolecular C–H Insertion Reaction
Miyazawa, T.; Imai, K.; Ito, M.; Takeda, K.; Anada, M.; Matsunaga, S.; Hashimoto, S.
HeteroCycles 2017, 95, 1211-1229. DOI: 10.3987/COM-16-S(S)72
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles2017-95-1211.png)
2016
Rapid Screening by Cell-Based Fusion Assay for Identifying Novel Antivirals of Glycoprotein B-Mediated Herpes Simplex Virus Type 1 Infection
Maeda, N.; Furukawa, A; Kakita, K.; Anada, M.; Hashimoto, S.; Matsunaga, S.; Kuroki, K.; Ose, T.; Kato, A.; Arii, J.; Kawaguchi, Y.; Arase, H.; Maenaka, K.
Biol. Pharm. Bull. 2016, 39, 1897-1902. DOI: 10.1248/bpb.b16-00533
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/bpb2016-39-1897.png)
Site- and Regioselective Monoalkenylation of Pyrroles with Alkynes via Cp*CoIII Catalysis
Tanaka, R.; Ikemoto, H.; Kanai, M.; Yoshino, T.; Matsunaga, S.
Org. Lett. 2016, 18, 5732-5735. DOI: 10.1021/acs.orglett.6b02997
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2016-18-5732.gif)
Enantio-and diastereoselective desymmetrization of α-alkyl-α-diazoesters by dirhodium(II)-catalyzed intramolecular C–H insertion
Miyazawa, T.; Minami, K.; Ito, M;, Anada, M.; Matsunaga, S.; Hashimoto, S.
Tetrahedron 2016, 72, 3939-3947. DOI: 10.1016/j.tet.2016.05.015
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/tetrahedron2016-72-3939.jpg)
Cp*CoIII-Catalyzed Dehydrative C–H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols
Bunno, Y.; Murakami, N.; Suzuki, Y.; Kanai, M.; Yoshino, T.; Matsunaga, S.
Org. Lett. 2016, 18, 2216-2219. DOI: 10.1021/acs.orglett.6b00846
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2016-18-2216.png)
Carbon Dioxide Utilization via Carbonate-promoted C–H Carboxylation
Banerjee, A; Dick, G. R.; Yoshino, T.; Kanan, M. W.
Nature 2016, 531, 215-219. DOI: 10.1038/nature17185
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/nature2016-531-215.jpg)
2015
Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols
Lin. L.; Yamamoto, K.; Mitsunuma, H.; Kanzaki, Y.; Matsunaga, S.; Kanai, M.
J. Am. Chem. Soc. 2015, 137, 15418-15421. DOI: 10.1021/jacs.5b11192
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2015-137-15418.jpg)
Cp*CoIII Catalyzed Site-Selective C–H Activation of Unsymmetrical O-Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes
Sun, B.; Yoshino, T.; Kanai, M.; Matsunaga, S.
Angew. Chem., Int. Ed. 2015, 54, 12968-12972. DOI: 10.1002/anie.201507744
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2015-54-12968.gif)
Dehydrative Direct C–H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis
Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; Matsunaga, S.; Kanai, M.
Angew. Chem., Int. Ed. 2015, 54, 9944-9947. DOI: 10.1002/anie.201503704
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2015-54-9944.jpg)
Cp*Co(III)-catalyzed Oxidative C–H Alkenylation of Benzamides with Ethyl Acrylate
Suzuki, Y.; Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M.
Tetrahedron 2015, 71,4552-4556. DOI: 10.1016/j.tet.2015.02.032
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/tetrahedron2015-71-4552.jpg)
A Cp*CoI2-dimer as A Precursor for Cationic Co(III)-catalysis: Application to C–H Phosphoramidation of Indoles
Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M.
Chem. Commun. 2015, 51, 4659-4661. DOI: 10.1039/C4CC10284C
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cc2015-51-4659.gif)
2014
Regiodivergent Kinetic Resolution of Terminal and Internal rac-Aziridines with Malonates under Dinuclear Schiff Base Catalysis
Xu, Y.; Kaneko, K.; Kanai, M.; Shibasaki, M.; Matsunaga, S.
J. Am. Chem. Soc. 2014, 136, 9190-9194. DOI: 10.1021/ja5039165
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2014-136-9190.gif)
Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence
Ikemoto, H.; Yoshino, T.; Sakata, K.; Matsunaga, S.; Kanai, M.
J. Am. Chem. Soc. 2014, 136, 5424-5431. DOI: 10.1021/ja5008432
*Featured by SJN news.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/jacs2014-136-5424.gif)
Air-Stable Carbonyl(pentamethylcyclopentadienyl)cobalt Diiodide Complex as a Precursor for Cationic (Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed C-2 Selective C–H Amidation of Indoles
Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M.
Adv. Synth. Catal. 2014, 356, 1491-1495. DOI: 10.1002/adsc.201301110
*Selected as cover picture.
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/advsynthcat2014-356-1491.gif)
Cobalt-Catalyzed C-4 Selective Alkylation of Quinolines
Yamamoto, S.; Saga, Y.; Andou, T.; Matsunaga, S.; Kanai, M.
Adv. Synth. Catal. 2014, 356, 401-405. DOI: 10.1002/adsc.201300991
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/advsynthcat2014-356-401.gif)
Enantioselective Synthesis of Spirooxindoles via Direct Catalytic Asymmetric Aldol-Type Reaction of Isothiocyanato Oxindoles
Kato, S.; Kanai, M.; Matsunaga, S.
Heterocycles 2014, 88, 475-491. DOI: 10.3987/COM-13-S(S)60
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles2014-88-475.jpg)
2013
Rh-Catalyzed Aldehyde-Aldehyde Cross-Aldol Reaction under Base-Free Conditions: In-Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation
Lin, L.; Yamamoto, K.; Matsunaga, S.; Kanai, M.
Chem. Asian J. 2013, 8, 2974-2983. DOI: 10.1002/asia.201300928
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/caj2013-8-2974.png)
Structure-activity relationship study of novel iminothiadiazolo-pyrimidinone antimicrobial agents
Paudel, A.; Kaneko, K.; Watanabe, A.; Matsunaga, S.; Kanai, M.; Hamamoto, H.; Sekimizu, K.
J. Antibiot. 2013, 66, 663-667. DOI: 10.1038/ja.2013.69
Cp*CoIII-Catalyzed C2-Selective Addition of Indoles to Imines
Yoshino, T.; Ikemoto, H.; Matsunaga, S.; Kanai, M.
Chem. Eur. J. 2013, 19, 9142-9146. DOI: 10.1002/chem.201301505
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cej2013-19-9142.gif)
Sultam Synthesis via Cu-Catalyzed Intermolecular Carboamination of Alkenes with N-Fluorobenzenesulfonimide
Kaneko, K.; Yoshino, T.; Matsunaga, S.; Kanai, M.
Org. Lett. 2013, 15, 2502-2505. DOI: 10.1021/ol4009848
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/ol2013-15-2502.gif)
Catalytic Asymmetric Synthesis of Spirooxindoles via Addition of Isothiocyanato Oxindoles to Aldehydes Under Dinuclear Nickel Schiff Base Catalysis
Kato, S.; Kanai, M.; Matsunaga, S.
Chem. Asian J. 2013, 8, 1768-1771. DOI: 10.1002/asia.201300251
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/caj2013-8-1768.gif)
Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines
Andou, T.; Saga, Y.; Komai, H.; Matsunaga, S. Kanai, M.
Angew. Chem., Int. Ed. 2013, 52, 3213-3216. DOI: 10.1002/anie.201208666
Featured by SYMFORM 2013/06
Featured by ワイリー・サイエンスカフェ
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2013-52-3213.gif)
A Cationic High-Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed C–H Bond Activation
Yoshino, T. Ikemoto, H.; Matsunaga, S.; Kanai, M.
Angew. Chem., Int. Ed. 2013, 52, 2207-2211. DOI: 10.1002/anie.201209226
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2013-52-2207.gif)
Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts
Matsunaga, S.; Shibasaki, M.
Synthesis 2013, 45, 421-437. DOI: 10.1055/s-0032-1316846
2012
Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols
Lin, L.; Yamamoto, K.; Matsunaga, S.; Kanai, M.
Angew. Chem., Int. Ed. 2012, 51, 10275-10279. DOI: 10.1002/anie.201205680
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2012-51-10275.gif)
Direct Catalytic Asymmetric Vinylogous Michael Reaction of α,β-Unsaturated γ-Butyrolactam under Dinuclear Nickel Schiff Base Catalysis
Tanabe, H.; Xu, Y.; Sun, B.; Matsunaga, S.; Shibasaki, M.
Heterocycles 2012, 86, 611-622. DOI: 10.3987/COM-12-S(N)58
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles2012-86-611.jpg)
Enantioselective Synthesis of 2,2-Disubstituted Terminal Epoxides via Catalytic Asymmetric Corey-Chaykovsky Epoxidation of Ketones
Sone, T.; Yamaguchi, A.; Matsunaga, S.; Shibasaki, M.
Molecules 2012, 17, 1617-1634. DOI: 10.3390/molecules17021617 (open access)
Catalytic Asymmetric Amination of Oxindoles under Dinuclear Nickel Schiff Base Catalysis
Mouri, S.; Chen, Z.; Matsunaga, S.; Shibasaki, M.
Heterocycles 2012, 84, 879-892. DOI: 10.3987/COM-11-S(P)66
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/heterocycles2012-84-879.jpg)
Catalytic Asymmetric Synthesis of Spirooxindoles by a Mannich-Type Reaction of Isothiocyanato Oxindoles
Kato, S.; Yoshino, T.; Shibasaki, M.; Kanai, M.; Matsunaga, S.
Angew. Chem., Int. Ed. 2012, 51, 7007-7010. DOI: 10.1002/anie.201203005
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2012-51-7007.gif)
Mg-catalyzed Enantioselective Benzylic C–H Bond Functionalization of Isoindolinones: Addition to Imines
Suzuki, Y.; Kanai, M.; Matsunaga, S.
Chem. Eur. J. 2012, 18, 7654-7657. DOI: 10.1002/chem.201200821
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/cej2012-18-7654.gif)
Lewis Acid Catalyzed Benzylic C–H Bond Functionalization of Azaarenes; Addition to Imines and Enones
Komai, H.; Yoshino, T.; Matsunaga, S.; Kanai, M.
Synthesis 2012, 44, 2185-2194. DOI: 10.1055/s-0031-1291041
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/synthesis2012-44-2185.gif)
Catalytic Asymmetric Total Synthesis of Chimonanthine, Folicanthine, and Calycanthine through Double Michael Reaction of Bisoxindole
Mitsunuma, H.; Shibasaki, M.; Kanai, M.; Matsunaga, S.
Angew. Chem., Int. Ed. 2012, 51, 5217-5221. DOI: 10.1002/anie.201201132
![](https://shuyu.kuchem.kyoto-u.ac.jp/wp-content/uploads/2024/04/acie2012-51-5217.gif)